Nov 12, 2016 - Amjad Ali · 20, 21, 62, 63. Anikate Sood · 79. Anil K. Sharma · 100. Anil Kumar · 89 ... C. Raman Suri · 73. Célia Regina Ãlvares Maltha ·. 47.
Proceedings of National Conference on
Recent Advances in Chemical Sciences
2016
11 & 12 November 2016
DEPARTMENT OF CHEMISTRY MAHARISHI MARKANDESHWAR UNIVERSITY, MULLANA, AMBALA-133207
PROCEEDINGS OF NATIONAL CONFERENCE ON RECENT ADVANCES IN CHEMICAL SCIENCES Theme: Chemistry as the Central Science and its Implementation in Future Research Fields
Dr. Rajshree Khare (Conference Director) Dr. Kuldeep Singh (Convener)
DEPARTMENT OF CHEMISTRY, MMEC MAHARISHI MARKANDESHWAR UNIVERSITY, MULLANA, AMBALA-133207
NAAC Accredited Grade “A” University
Proceedings of National Conference on Recent Advances in Chemical Sciences Editors: Dr. Rajshree Khare and Dr. Kuldeep Singh Copyright © 2016 ISBN 978-93-5267-361-2 First published in India by Chemistry Department, M M University Mullana – 133207 India. All rights reserved. No part of this publication may be reproduced or distributed in any form or by any means, or stored in a data base or retrieval system, without the prior written permission of the Convener/ department/University. However, Authors are allowed to submit only their article to scientific repositories/ their website/Researchgate with giving proper citation to this publication. Cover (illustration) by Dr. Pankaj Kumar and Dr. Kuldeep Singh MRSC. Printed in India. This publication is designed to provide accurate and authoritative information for Researchers and scientists working in chemical sciences. It is sold under the express understanding that any decisions or actions you take as a result of reading this book must be based on your commercial/scientific judgement and will be at your sole risk. The authors/Editors/Conference Convener/ Organization committee/ Department/ University will not be held responsible for the consequences of any actions and/or decisions taken as a result of any information given or recommendations made. Authors has moral rights and responsibility for their articles for plagiarism, trueness, correctness, reproducibility of experiments, results.
ABOUT MAHARISHI MARKANDESHWAR UNIVERSITY, MULLANA, AMBALA Maharishi Markandeshwar University (MMU) is a leading University in North India and has become a symbol of quality education in technical, medical and other professional streams. MMU has been accredited by NAAC as Grade "A" university. Since its inception, the University is committed to excel in research, innovation and skill development. Our Industry oriented education system helps us to make our students leaders in the professional world. The University is offering plethora of courses through its various teaching institutions spreading over three different Campuses at Mullana, Sadopur and Solan. The constituent institutions of the University are MM Engineering College; MM Institute of Computer Technology & Business Management (MCA); MM College of Dental Sciences & Research; MM Institute of Physiotherapy & Rehabilitation; MM Institute of Computer Technology & Business Management (Hotel Management); MM Institute of Medical Sciences & Research; MM Institute of Management; MM College of Nursing; MM College of Pharmacy; and MM Institute of Nursing, Mullana, Ambala. These institutes are also approved by the regulatory bodies like Medical Council of India, Dental Council of India, Indian Nursing Council, Indian Association of Physiotherapists, All India Council for Technical Education, DSIR etc .
ABOUT THE CHEMISTRY DEPARTMENT The Department of Chemistry is a premier department of the university. It was initially established in 1995 as one of the Department under Applied Sciences. It started working as an independent University Department in 2008. The Department offers Post Graduate (M. Sc. in Chemistry) and PhD programs. The Department also caters to first year Engineering and Diploma-B.Tech., B.Sc., Integrated students, Biotechnology Department for chemistry courses. The Department has 22 members team of dedicated and competent faculty with aim to impart quality education among science students.
CONTACT ADDRESS: Dr. Rajshree Khare Professor & Head Department of Chemistry, MMEC, Maharishi Markandeshwar University Mullana- Ambala, 133-207 (Haryana) www.mmmumullana.org www.mmu.ac.in
UNIVERSITY CONTACT NUMBERS Toll-free No. 1800-2740-240 Landline: 01731-274475,76,77,78, 01731-304100 (For all users except BSNL customers) Mobile : +91-8059930001, 02, 03, 04, 05, 06 Fax. No. 01731-274375
CONTENTS NCRACS-2016 Organizing Committee MESSAGES KEYNOTE Dr. Rajender S. Sangwan, F.N.A.A.S., F.N.A.Sc.
1 2
Bio-Inspired Chemistry for Grand Challenges in Food, Energy and Environment- New Waves of Enthusiasm and Innovations
3
PLENARY LECTURES Prof. Ravi Bhushan, CChem, FRSC, FNASc Resolution and Control of Enantiomeric Purity
5 6 7
Prof. N. K. Ralhan Academia – Industry Interaction
8 9
Dr. M. R. Maurya
10
Catalytic Aspects of Polymer Supported Vanadium Complexes and Their Future
11
Dr. Himadri B. Bohidar
12
Soft Interaction Induced Phase Separation in Biopolymers and Design of New Biomaterials
13
INVITED TALKS Dr. Akash Deep
15 16
Application of Advanced Nanomaterials for Sensing Applications
17
Dr. Sonal Singhal
18
Magnetically Retrievable Nanocomposites: An Approach towards Green Catalysis
19
Dr. Amjad Ali
20
Chemical Transformation of Triglycerides and Glycerol Via Mixed Metal Oxide based Heterogeneous Catalysts
21
Dr. Shaibal Banerjee
22
Azido Esters as an Energetic Plasticizers
23
Dr. Nitin Singhal
24
Immobilization of α-Amylase on Magnetic Nanoparticles for Enhanced Reusability in Bio-Catalytic Processes
25
Dr Uma Shanker
26
Green Synthesis Of Different Transition Metal Oxide Nanoparticles: Potential Catalysts For Removal Of Organic Colorants From Water
27
Dr. Amardeep Singh
28
Evaluation of Metal-Organic Frameworks for Hydrogen Storage
29
Dr. Asish Kumar Sharma
30
Academic - Industrial Research Collaborations
30
Actuating Materials: Conversion of Light and Heat Energy into Mechanical Energy
31
ORAL PRESENTATIONS
33
Design and synthesis of modified amino acids and peptides
34
A Footstep Towards the Development of Eco-Friendly Lubricant Additives from Biomaterials
34
Extraction and Spectrophotometric Determination of Molybdenum (VI) using 3-Hydroxy-2-[-3-(4methoxyphenyl)-1-phenyl-4-pyrazolyl]-4-oxo-4H-1-benzopyran as a Chelating Agent Waste Water Treatment Using Cuprous Oxide Nanomaterials
35
Nitric Oxide Dioxygenation Reactions and Their Mechanistic Insights
36
35
i
Biological Patents with Special Reference to Practical and Ethical Implications
37
Synthesis of Novel Ketomethylene N Domain Selective Ace Inhibitors
37
Anion Receptors-An Overview
38
Total volatile organic compounds (TVOCs) in Indoor and Outdoor Urban Atmospheres at a Terai Region Of Northern India Review on Catalytic Chemical Vapour Deposition (CCVD) Growth of Single Walled Carbon Nanotubes and their Characterization
38
INVITED ARTICLES Professor Sabyasachi Sarkar
41 42
Chemistry: Processing Everything Including Life
43
Natural Abenquines and Analogues as Potent Algicidal
45
Total Synthesis of the Antitumor Antibiotic Basidalin
46
Novel Non-Halogenated Flame Retardant For PCB
47
Dr. Soumita Ghosh
48
Exploring Biology Using Chemistry: Lessons from Metabolomics and Proteomics
49
A Novel Aspirin-Derived Small Molecule as A Potential Therapeutic for Colorectal Cancer
50
POSTER PRESENTATIONS
51
Electronic Structure Studies of L And D- Alanine.
52
PTSA Catalysed Solvent-Free Synthesis and Biological Evaluation of Some 5-Aminopyrazoles
53
CuO Nanostructures of Variable Shapes as an Efficient Catalyst for [3+2] Cycloaddition of Azides with Terminal Alkyne Spectrophotometric Determination of Pd(II) In Micellar Media by Sodium-1-Methyl-1-Propylthioxanthate
53
Elastic Behavior of La2-xSrxCuO4 (x=0.10-0.20)
54
Removal of Chromium III Ion from Waste Water using Gossypium herbacium as a Biosorbent
54
Structural Properties of Tb Incorporated ZnO Nanoparticles: An EXAFS And XPS Study
55
Heavy Metals in Environment and its Microbial Bioremediation
56
A Novel Method of The Synthesis of Titanium Dioxide Nps
56
Recent Innovative Approaches and Role of Microbes Towards Ecofriendly Remediation of Heavy Metals
57
Synthesis and Anti-Microbial Evaluation of Benzimidazole-1-Substituted Hydrazide Derivatives
57
Synthesis of Some Secondary Amines
58
Current Channelling Effect in Magnetotelluric Field Data
58
Lipid Based Peptidomimetics As Antimicrobial Agents
59
New Heterobimetallic Complexes and Their Interaction with DNA
59
The Field Study on The Discharge and Using of Agricultural Chemicals and Effects on The Agricultural Environment Point of Use Wastewater Treatment Using Agglomerated Nanoparticles of Titanium (IV) oxide and Blotter Paper Impregnated with Silver Nanoparticles in Colum Mode Effect of Solvents on Photo-catalytic Properties of SnO2 Nanoparticles Synthesized by Chemical Coprecipitation Method Sulphate and Cerium Impregnated Ti/ZrO2 as Heterogeneous Catalyst for Glycerol Esterification
60
Inorganic Hybrid Materials Based on Mesoporous Silica Composites for Humidity Sensing Applications
61
Spectrofluorimetric Determination of Al3+ Using 3-hydroxy-2-(4-methoxy phenyl)-4H-chromen-4-one as Analytical Reagent. Well-defined Quantum Dots and Morphological Control of Nanomaterials
62
39
54
60 61 61
62
Perspective of Plant Based Home Made Organic Pesticides
63
Green Solvents for Organic Synthesis
63
Synthesis and Characterization of Peptide Derivatives of Quinazolinone
64
Synthesis and Characterization of Novel Zirconium Antimonoarsano- tungstate Zr[SbAsW] Salt
64
Biomass Generation from Sugarcane, Rice and Wheat Crops: Consequences of Removal Practices and Alternatives DFT Based Analysis for The Regio- and Stereoselective Synthesis of Tetrasubstituted Isoxazolidines From Cinnamoyl Piperidine Derivatives Potentiometric Determination of Lead (II) Ion using 2-[(4-Chloro-Phenylimino)-Methyl]-Phenol as an electroactive Material Transition Metal Complexes of 1-(2-Methylphenyl)-4, 4, 6-Trimethyl Pyrimidine-2-thione : Synthesis and Biological Studies A Review on Synthesis and Characterization of ZnO Nanoparticles
65
Clerodendrum serratum (L.) Moon. A Review on Conventional Uses and Scientific Findings
68
Destabilization Mechanism of Alzheimer’s Aβ42 Protofibrils With a Small-Molecule Inhibitor: A Molecular Dynamics Simulation Study Synthesis and Antimicrobial Screening of Thiazolidinone Derivatives
68
Subchronic Toxicity Studies of Aqueous Extract of Alangium salvifolium Leaves in Rats
69
Synthesis, Characterization of Novel 3-(4-Substituted Phenyl)-1-(6-Substituted Benzothiazol-2-yl)-1HPyrazole-4-Carbaldehyde As Potential Antimicrobial Agent Protective Effects of Linoleic acid on toxicity Caused by Acrylamide in Rats
70
Anodic Stripping Voltammetry of Anti-VI Antibody Functionalized CdTe Quantum Dots for Specific Monitoring of Salmonella enterica serovar Typhi Sonochemistry: The Non-Conventional Method of Organic Synthesis
71
Synthesis and Characterisation of Ce(III) Doped Polyvinylpyrollid-one Capped ZnS Nanoparticles
72
Electronic Structure Studies of Aspirin and Paracetamol.
72
Uniform Dispersion of Anisotropic CuO/SBA-15 Nanocomposites for Nitroaromatic Reduction
73
Evaluation of Phytochemicals and TLC optimization in Alstonia scholaris and Caesalpinia crista of Western Himalayan Region Assessing the Effect of DE-Loop Mutation (D59P) in the Amyloid Aggregation Propensity of β2Microglobulin with Molecular Dynamics Simulations Synthesis and Characterisation of Molecularly Imprinted Polymer Nanoparticles for Streptomycin for Use as Solid Phase Extraction Materials Streptomyces albogriseolus as a Potential Bioremediation Agent for Sulfosulfuron
74
Synthesis of 3-substituted chromone derivatives for their antibacterial studies.
76
Synthesis, Characterisation and Analytical Applications of Novel Potentiometric Sensor Chromium (III) Boratotungstophosphate Formulation and Characterisation of Dual Drug Loaded Lipid Based Carrier System
76
Chemical Analysis of Municipal Water Samples of Gurgaon
77
To Study the Effect Of Urtica Dioica Extract On Diabetes–Mediated Alteration in Glucose Transporter.
78
Lipophilic peptide Multi-Nucleoside reverse transcriptase inhibitor conjugates synthesis to combat HIV resistance Crystallite Size Dependence on Photocatalytic and Antimicrobial Activity of Microemulsion Mediated Synthesized ZnO Nanoparticles Annealed at Different Temperatures Synthesis and Reactivity of Ru-DMSO Complexes
78
Wound Healing and Hemolytic Activity of Different Extracts of Arnebia benthamii
81
Synthesis of Nanomaterials by Fabricating AAO Membranes
81
Asia’s Fight Against Disasters: An Indigenous Approach
81
Synthesis, Characterization and Biological Evaluation of N- Substituted Heterocyclic beta-Lactam Derivatives
82
66 67 67 67
69
70
71
74 75 75
77
79 80
iii
Preparation of some Benzo 1,5-Diazepine
82
Extractive Oxidative Desulfurization of fuels with Hydrogen Peroxide in presence of catalysts
83
Bacteriophage Conjugated Metal Organic Framework for Sensitive Detection of S. arlettae
84
A Novel Fluorescent Sensing Technique for Dipicolinic acid
84
CoMFA/ CoMSIA Studies on Peripherally Acting CB1 Receptor Antagonists as Anti-Obesity Agents
85
Nematode Paradoxical Activity of Naturally Occuring Biologically Active Compounds
86
2, 5-Disubstituted-1,3,4-Oxadiazoles as DNA Photo-Cleaving Agents
86
2-(3, 5-Dimethyl-1H-pyrazol-1-yl)-1-arylethanones as Potential Anticancer Agents
87
Azoles: Introduction, Current and Future Scope
87
Synthesis and Anticancer Activity of Some Novel 1,3,5-Trisubstituted pyrazolines using MDA-MB-231 and Hep-G2 cancer cell lines Graphene and Its Electronic Properties
88
Synergistic Effect of THF with Amines as Vapour Phase Corrosion Inhibitor for Mild Steel under Atmospheric Conditions at High Temperature Study of Magnetic Properties of Mixed Cobalt-Zinc Ferrites Synthesized By Solid State Reaction Technique. Solubility Behaviour of Cellulose-Reinforced Starch-PVA Blends with Insertion of Fly-Ash
89
Colorimetric Determination of Vitamin C Using Fe(II)-5-Chloro-7-Iodo-8-Hydroxyquinoline Complex
91
Conductance studies of Li+ and Na+ in Acetonitrile and Nitromethane binary mixtures at 298.15 K
92
Removal of Pesticides from Water Using Low Cost Adsorbents
93
Synthesis, Characterisation and Applications of 3D Transition Metal Oxide Nano Particles
93
Theoretical Studies On Structure Of Octacarboranes Dianions
94
Comparative study on modeling growth inhibition activity using physicochemical and connectivity indices
94
Flame retardant polymeric materials Immobilization of Cadmium ions with ordinary Portland cement
95 95
UG/PG POSTER COMPETITION
99
Factors That Control the Reactivity of Cobalt(III)-Nitrosyl Complexes in Nitric Oxide Transfer and Dioxygenation Reactions Chemistry of Life
100
Mechanistic Insight into the Nitric Oxide Dioxygenation Reaction of Nonheme Fe(III)–Superoxo and Mn(IV)–Peroxo Complexes Nitric Oxide Dioxygenation Reactions and Their Mechanistic Insights
101
Clouding and Aggregation of Triton X-100 Micelles: Effect of Additives Sugar Based Low Melting Mixtures as Green Solvents in The Hantzsch Synthesis of Substituted 1,4Dihydropyridines
AUTHOR INDEX
88
89 90
100
102 102 103 105
NCRACS-2016
Author Index Bonamali Pal · 75 Brijesh Singh · 91
A A. K. Sharma · 54, 74 A. Sharma · 57 A. Singh · 29, 35 A.K. Gupta · 4 A.K. Minocha · 95, 97 Aaydha C. Vinayaka · 73 Ahmad Husain · 31 Akash Deep · 16, 73, 85, 86 Amalyn Nain-Perez · 47 Amardeep Singh · 28 Amit Bhardwaj · 95 Amit Kumar · 62 Amit L Sharma · 86 Amit Masih · 38 Amjad Ali · 20, 21, 62, 63 Anikate Sood · 79 Anil K. Sharma · 100 Anil Kumar · 89 Anil Sharma · 77 Anirban Deb · 87 Anjana Jadaun · 72 Anju Parmar · 78 Anshul Bansal · 55 Anup Timsina · 54 Anupamjeet Kaur · 55 Anupreet Kaur · 56 Arshid Nabi · 66 Arun K. Sharma · 52 Arvind Kumar Tiwari · 56 Asar Ahmed · 35, 36 Ashwani Kumar · 92 Ashwanti Devi · 58, 59 Asish Kumar Sharma · 30 Avijit Banerji · 68 Avnish Arora · 4, 69 Avnish Kumar Arora · 58
B B .K. Aggarwal · 62 B R Nautiyal · 84 Bhoopendra Singh · 56 Bhupender Pal · 55 Bhupender S. Chhikara · 80 Bhupesh Goyal · 55, 70, 76 Bhupinder Kapoor · 59
C C. Raman Suri · 73 Célia Regina Álvares Maltha · 47 Charu Agarwal · 79
D D. O. Shah · 81 D. P. Pandey · 82 Daniel Plano · 52 Deepak Kumar Tyagi · 60 Deepika Jamwal · 64 Deepika Sharma · 61 Deepkamal N. Karelia · 52 Deepti Goyal · 34, 55, 76 Diksha · 69, 74 Divyam Semwal · 102 Diwakar Aggarwal · 100 Dr.Udayabanu. M · 80
H. Singh · 94 Hardeep Anand · 92 Hardeep Singh Tuli · 83 Harish K. Sharma · 14 Harsimranjot Kaur · 63 Himadri B. Bohidar · 12
I Inderjeet · 87 Indrani Das Sen · 102 Indu Sharma · 58, 59
J J. Ashwin Kumar · 103 J. K. Mishra · 57 Jaime A. M. Acosta · 48 Jasveen Khanduja · 87 Jaswant Ray · 62 Joginder Singh · 4, 62 John Boukouvalas · 48 Jyoti Sharma · 4, 69, 81 Jyotsana Mehta · 86
E
K
Edward D. Sturrock · 37 Ekta Poonia · 63
Karamjit Singh · 63 Karan Singh · 72 Kelly Chibale · 37 Keykavous Parang · 80 Km Abida · 63 Krishan Kumar · 63 Kulbir · 84 Kuldeep Kaur · 64, 74 Kuldeep Singh · 2, 3, 4, 14, 20, 37, 60, 71, 84, 90 Kumar Sunil · 88 Kusum · 82
G Gagandeep Kaur · 71 Gajanan Pandey · 56 Girish Chandra · 39, 40, 61 Girish Chandra Sharma · 61 Giuseppe Forlani · 47 Gomathi Shridhar · 103 Gopal Singh Bisht · 61
L H H. K. Sharma · 4, 14, 66 H. Kumar · 90 H. S. Bhatti · 63
Lak Shin Jeong · 39 Lakshmy Ravishankar · 103 Lata Taneja · 101 Leena Thakur · 91
105
NCRACS-2016 Luiz C. A. Barbosa · 48 Luiz Claudio A. Barbosa · 47
M M. A. Rather · 82 M. Kumar · 88 M. R. Maurya · 10 Mange Ram Yadav · 87 Manoj K. Pandey · 52 Manoj Kumar · 83 Manu Vashishtha · 81 Mayank Kinger · 4, 89 Mayank Kumar Sharma · 87 Mayank Pratap Singh · 49 Meena Rani · 65 Meera · 65 Megha Bedi · 83 Mukta Gupta · 66
N N. Agnihotri · 35 N. K. Ralhan · 8 N. Sharma · 66 Nadeem Sharma · 4, 19, 95 Narender Chaudhry · 87 Narender singh · 92 Narinder Kaur · 100 Navnit Kumar Mishra · 77 Neha Bhardwaj · 85, 86 Nidhi Dahiya · 100 Nirankar Singh · 4, 67 Nisha · 84 Nitin Singhal · 24 Nivedita Acharjee · 68 Nivedita Agnihotri · 4
O O. P. Singh · 54, 74
P P Dogra · 66 Pankaj · 54 Pankaj Kumar · 3, 4, 36 Pankaj Thakur · 64 Pawan K.Bharti · 62 Pernita Dogra · 4, 69
106
Pooja Rani · 64 Pooja Sethi · 69 Pooja Sharma · 4 Pooja Yadav · 84 Poonam Dogra · 72 Prabha Mehta · 56 Prashant Murumkar · 87 Priya Yadav · 100 Priyanka · 69
R R. Agnihotri · 35 R. P. Singh · 82 Radha Jayaram · 102 Raj K. Singh · 34 Raj Kumar Tiwari · 70, 76 Rajender S. Sangwan · 2 Rajkamal · 35 Rajneesh Kaur · 84 Rajni K. Sharma · 37 Rajshree Khare · 2, 4, 5, 18, 19, 58, 69, 83 Rakesh Yadav · 84 Raman Singh · 4, 37, 71, 84 Ramesh Muddala · 48 Ranjana Aggarwal · 55 Ravi Bhushan · 6 Reena Gupta · 71 Renu Bala · 72 Ridhima Arya · 77 Ritu · 38, 66 Ritu Bala · 38 Rohit Manhas · 59 Ross G. Douglas · 37 Rupal Sharma · 56
S S. K. Saini · 90 Sabyasachi Sarkar · 44 Sadhana Shrivastava · 72 Sahil Gupta · 80 Sakshi Nagpal · 90 Sakshi Wadhava · 60 Sang Wook Kim · 89 Saniya Ahluwalia · 83 Sanjeev K. Bhardwaj · 86 Satish Kumar · 73, 92 Satish Kumar Pandey · 73 Satnam Singh · 75 Satyender Kumar Yadav · 73 Savita Chahal · 78
Savita Ladage · 103 Seema Maheshwari · 74 Shaibal Banerjee · 22 Shantu Amin · 52 Sharad Sharma · 90 Shikha · 74 Shiwani, · 101 Shweta Mutreja · 4 Shweta Sareen · 75 Silpi Chanda · 70, 76 Simranjeet Singh · 76 Simrat Kaur · 77 Simrat Preet Kaur · 77 Sita Sharan Patel · 80 Sonal Singhal · 18 Sonia Nain · 78 Soumita Ghosh · 50 Sukhmani Mann · 55 Sumit Kumar · 78 Sumit Sood · 72 Suniba Shuaib · 70, 76 Sunil Kumar · 102 Surender Duhan · 63 Sushil Kumar · 89 Sutapa Mandal · 68
U Udayabanu M · 70 Uma Shanker · 26 Umesh Yadav · 102
V V. Beniwal · 88 V. Kumar · 88 Vaibhav Wadhwa · 102 Vibha Kumari · 94 Vinit Mishra · 90 Vinit Prakash · 4 Vinod Kumar · 4, 72, 83, 88, 89 Vishal Mutreja · 4, 75 Vivek Sheel · 4, 58, 69 Vivek Sheel Jaswal · 69 Vivek Singh · 58, 59
Y Y. Singh · 82
Proceedings of National Conference on Recent Advances in Chemical Sciences
