10.1071/CH10175_AC © CSIRO 2011 Australian Journal of Chemistry, 2011, 64(1), 104–118
Accessory Publication
Crystal Structures and Luminescence Behavior of d10 Metal-Organic Complexes with Multi-Pyridine Ligands
Chunfeng Yan,AB Qihui Chen,A Lian Chen,A Rui Feng,A Xiaochen Shan,A Feilong Jiang,A,C Maochun Hong A,C A
Key Laboratory of Optoelectronic Materials Chemistry and Physics,
B
The Research Center of Applied Chemistry,
Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fuzhou 350002, China. C
Corresponding authors. Email:
[email protected];
[email protected]
Figure A1. PXRD patterns of complexes 1-6 (a: complex 1, b: complex 2, c: complex 3, d: complex 4, e: complex 5, f; complex 6)
Intensity
458
400
450
500
550
600
650
700
Wavelength/nm
Figure A2. Solid emission spectrum of terpy ligand at room temperature.
Intensity
CH2Cl2 MeOH THF DMF MeCN acetone
350
400
450
500
550
600
Wavelength/nm
Figure A3. The emission spectra of complex 1 in different solvents.
650
Intensity
495
400
450
500
550
600
650
700
Wavelength/nm
Figure A4. Solid emission spectrum of tpt ligand at room temperature.
Intensity
MeOH THF DMF MeCN CH2Cl2
300
350
400 450 500 Wavelength/nm
550
600
650
Figure A5. The emission spectra of complex 4 in different solvents.
Intensity
CH2Cl2 MeOH THF MeCN DMF
300
400
500
600
Wavelength/nm
Figure S6.The emission spectra of complex 6 in different solvents.
700
