Easy Composites MSDS – Epoxy Tooling Gel Coat - Revision 3 - Revision date
10-June-2013 - Page 1 of 6. IMPORTANT: THIS DOCUMENT CONTAINS MSDS
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Easy Composites MSDS – Epoxy Tooling Gel Coat ‐ Revision 3 ‐ Revision date 10‐June‐2013 ‐ Page 1 of 6
IMPORTANT: THIS DOCUMENT CONTAINS MSDS FOR THE RESIN AND THE HARDENER. FOR HARDENER MSDS SCROLL THROUGH THE DOCUMENT TO PAGE (4) ONWARDS.
SAFETY DATA SHEET Epoxy Tooling Gel Coat 1. IDENTIFICATION OF THE SUBSTANCE / PREPARATION AND THE COMPANY Product name Company
Email Telephone
Epoxy Tooling Gel Coat
Easy Composites Ltd Unit 39 Park Hall Business Village Longton, Stoke‐on‐Trent ST3 5XA United Kingdom
[email protected] +44 (0)1782 454499
2. HAZARDS IDENTIFICATION Main hazards
Irritating to eyes and skin. May cause sensitisation by skin contact. Toxic to aquatic organisms, may cause long‐term adverse effects in the aquatic environment.
3. COMPOSITION / INFORMATION ON INGREDIENTS Hazardous ingredients
Concentration
CAS
EINECS
CAS Symbols/Risk phrases
Bisphenol F‐epichlorohydrin resin, mw 2000 mg/kg
12. ECOLOGICAL INFORMATION Ecotoxicity Bisphenol A‐(epichlorhydrin) (reaction product)
Toxic to aquatic organisms, may cause long‐term adverse effects in the aquatic environment. Green algae EC50/96h = 220 mg/l Rainbow trout LC50/96h = 1.5 ‐ 7.7 mg/l
13. DISPOSAL CONSIDERATIONS General information
Dispose of in compliance with all local and national regulations.
14. TRANSPORT INFORMATION Proper Shipping Name
ADR/RID
IMDG
ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S, . UN 3082 Class 9
Packing group III Hazard ID 90
Easy Composites MSDS – Epoxy Tooling Gel Coat ‐ Revision 3 ‐ Revision date 10‐June‐2013 ‐ Page 3 of 6
UN 3082 Class 9 EmS Code F‐A S‐F IATA UN 3082 Class 9 Packing Instruction (Cargo) 914 Packing Instruction (Passenger) 914
Packing group III Marine pollutant: . Packing group III Subsidiary risk ‐ Maximum quantity: 450L Maximum quantity: 450L
15. REGULATORY INFORMATION Labelling Symbols
The product is classified in accordance with 67/548/EEC. Xi ‐ Irritant; N ‐ Dangerous for the environment
Risk phrases
R36/38 ‐ Irritating to eyes and skin. R43 ‐ May cause sensitisation by skin contact. R51/53 ‐ Toxic to aquatic organisms, may cause long‐term adverse effects in the aquatic environment. S24 ‐ Avoid contact with skin. S29 ‐ Do not empty into drains. S37 ‐ Wear suitable gloves.
Safety phrases
16. OTHER INFORMATION Text of risk phrases in Section 3.
Further information
Further information
R36/37/38 ‐ Irritating to eyes, respiratory system and skin. R36/38 ‐ Irritating to eyes and skin. R43 ‐ May cause sensitisation by skin contact. R51/53 ‐ Toxic to aquatic organisms, may cause long‐term adverse effects in the aquatic environment. The information supplied in this Safety Data Sheet is designed only as guidance for the safe use, storage and handling of the product. This information is correct to the best of our knowledge and belief at the date of publication however no guarantee is made to its accuracy. This information relates only to the specific material designated and may not be valid for such material used in combination with any other materials or in any other process.
This document differs from the previous version in the following areas: 2 ‐ hazardous ingredients.
Easy Composites MSDS – Epoxy Tooling Gel Coat ‐ Revision 3 ‐ Revision date 10‐June‐2013 ‐ Page 4 of 6
SAFETY DATA SHEET Epoxy Tooling Gel Coat Hardener 1. IDENTIFICATION OF THE SUBSTANCE / PREPARATION AND THE COMPANY Product name Company
Email Telephone
Epoxy Tooling Gel Coat Hardener
Easy Composites Ltd Unit 39 Park Hall Business Village Longton, Stoke‐on‐Trent ST3 5XA United Kingdom
[email protected] +44 (0)1782 454499
2. HAZARDS IDENTIFICATION Main hazards
Causes burns. May cause sensitisation by skin contact. Very toxic to aquatic organisms, may cause long‐term adverse effects in the aquatic environment. Possible risk of impaired fertility.
3. COMPOSITION / INFORMATION ON INGREDIENTS Hazardous ingredients 3,6,9,12‐Tetra‐ azatetradecamethylenediamine 2,2'‐Iminodiethylamine (2,2'‐Iminodi(ethylamine)) 4,4'‐Isopropylidenediphenol
Concentration 50 ‐ 100%
CAS 4067‐16‐7
EINECS 223‐775‐9
CAS Symbols/Risk phrases C; R34 R43 N; R50/53
1 ‐ 30% 1 ‐ 30%
111‐40‐0 80‐05‐7
203‐865‐4 201‐245‐8
Xn; R21/22 C; R34 R43 Repr Cat 3; R62 Xi; R37‐41 R43
4. FIRST AID MEASURES Skin contact Eye contact Inhalation Ingestion
Causes burns. Wash off immediately with plenty of soap and water. Remove contaminated clothing. Seek medical attention if irritation or symptoms persist. Causes burns. Causes severe inflammation and may damage the cornea. Seek medical attention. Inhalation of vapour may cause shortness of breath. Move the exposed person to fresh air. Seek medical attention. Ingestion causes burns to the respiratory tract. DO NOT INDUCE VOMITING. If swallowed, seek medical advice immediately and show this container or label.
5. FIRE FIGHTING MEASURES Extinguishing media Fire hazards Protective equipment
Use as appropriate: carbon dioxide (CO2), dry chemical, foam. Corrosive. Burning produces irritating, toxic and obnoxious fumes. Wear suitable respiratory equipment when necessary.
6. ACCIDENTAL RELEASE MEASURES Personal precautions Environmental precautions Clean up methods
Ensure adequate ventilation of the working area. Evacuate personnel to a safe area. Wear suitable protective equipment Do not allow product to enter drains. Prevent further spillage if safe. Absorb with inert, absorbent material. Transfer to suitable, labelled containers for
Easy Composites MSDS – Epoxy Tooling Gel Coat ‐ Revision 3 ‐ Revision date 10‐June‐2013 ‐ Page 5 of 6
disposal. Clean spillage area thoroughly with plenty of water.
7. HANDLING AND STORAGE Handling Storage
Avoid contact with eyes and skin. Ensure adequate ventilation of the working area. Keep in a cool, dry, well ventilated area. Keep containers tightly closed.
8. EXPOSURE CONTROLS / PERSONAL PROTECTION Exposure limits 2,2'‐Iminodiethylamine (2,2'‐Iminodi(ethylamine))
Engineering Measures Respiratory protection Hand protection Eye protection Protective equipment
WEL 8‐hr limit ppm: 1 WEL 15 min limit ppm: ‐
WEL 8‐hr limit mg/m3: 4.3 WEL 15 min limit mg/m3: ‐
Ensure adequate ventilation of the working area. Wear: Self‐contained breathing apparatus. Chemical resistant gloves (PVC) Approved safety goggles. Wear chemical protective clothing.
9. PHYSICAL AND CHEMICAL PROPERTIES Description Colour Odour Relative density Viscosity
Liquid. Clear Ammoniacal. 1.02 350 mPa.s (25°C)
10. STABILITY AND REACTIVITY Stability
Stable under normal conditions.
11. TOXICOLOGICAL INFORMATION Toxicological information 3,6,9,12‐Tetra‐azatetradecamethylenediamine Corrosivity
Oral Rat LD50 = 1600 mg/kg Causes burns.
12. ECOLOGICAL INFORMATION Ecotoxicity 3,6,9,12‐Tetra‐azatetradecamethylenediamine
Daphnia EC50/48h = 18 mg/l g/l
13. DISPOSAL CONSIDERATIONS General information
Dispose of in compliance with all local and national regulations.
14. TRANSPORT INFORMATION Proper Shipping Name
AMINES, LIQUID, CORROSIVE N.O.S,.
ADR/RID
IMDG
UN 2735 Class 8 UN 2735 Class 8
Packing group III Hazard ID 80 Packing group III Marine pollutant: .
Easy Composites MSDS – Epoxy Tooling Gel Coat ‐ Revision 3 ‐ Revision date 10‐June‐2013 ‐ Page 6 of 6
EmS Code F‐A S‐B IATA UN 2735 Class 8 Packing Instruction (Cargo) 820 Packing Instruction (Passenger) 818
Packing group III Subsidiary risk ‐ Maximum quantity: 60L Maximum quantity: 5L
15. REGULATORY INFORMATION Labelling Symbols
The product is classified in accordance with 67/548/EEC. C ‐ Corrosive; N ‐ Dangerous for the environment
Risk phrases
R34 ‐ Causes burns. R43 ‐ May cause sensitisation by skin contact. R50/53 ‐ Very toxic to aquatic organisms, may cause long‐term adverse effects in the aquatic environment. R62 ‐ Possible risk of impaired fertility. S24 ‐ Avoid contact with skin. S26 ‐ In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. S28 ‐ After contact with skin, wash immediately with plenty of soap and water. S29 ‐ Do not empty into drains. S36/37/39 ‐ Wear suitable protective clothing, gloves and eye/face protection. S45 ‐ In case of accident or if you feel unwell, seek medical advice immediately (show the label where possible).
Safety phrases
16. OTHER INFORMATION Text of risk phrases in Section 3.
Further information
Further information
R21/22 ‐ Harmful in contact with skin and if swallowed. R34 ‐ Causes burns. R37 ‐ Irritating to respiratory system. R41 ‐ Risk of serious damage to eyes. R43 ‐ May cause sensitisation by skin contact. R50/53 ‐ Very toxic to aquatic organisms, may cause long‐term adverse effects in the aquatic environment. R62 ‐ Possible risk of impaired fertility. The information supplied in this Safety Data Sheet is designed only as guidance for the safe use, storage and handling of the product. This information is correct to the best of our knowledge and belief at the date of publication however no guarantee is made to its accuracy. This information relates only to the specific material designated and may not be valid for such material used in combination with any other materials or in any other process. This document differs from the previous version in the following areas: 15 ‐ symbols. 16 ‐ text of risk phrases in Section 2.
