Dec 3, 2015 - WHMIS Classes. : Not Listed. CEPA DSL. : Not Listed. : Not Listed ... Symbol of Danger: Xn. Canadian Non-Domestic Substances. List (NDSL).
SAFETY DATA SHEET
Disperse Blue 3 (C.I. 61505)
I – IDENTIFICATION Manufacturer’s Name: Manufacturer’s Address: Telephone Number: Emergency Phone Number: Effective Date: Product Name: Chemical Family: Recommended Use: Restrictions on Use: CAS Registry #: DOT Hazardous Shipping Classification:
Fibro Chem, LLC 1521 E. Walnut Ave. Dalton, GA 20721 (706)-278-3514 / (706)-226-9235 (CHEMTREC) 1-800-424-9300 December 3, 2015 Disperse Blue 3 (C.I. 61505) Disperse dye Textile dye For R&D use only. Not for drug, household or other uses 2475-46-9 Not Hazardous per DOT Not Regulated
II – HAZARDS IDENTIFICATION GHS CLASSIFICATION Category 1 - Skin sensitization Category 1 - Aquatic toxicity Category 2A - Serious Eye Damage/Irritation Category 5 - Acute toxicity/inhalation Category 4- Acute toxicity/oral WARNING: Possible Eye, Skin & Respiratory Irritant. May be harmful if swallowed. WARNING
HAZARD STATEMENT H302 Harmful if swallowed H317 May cause an allergic skin reaction H319 Causes serious eye irritation H400 Very toxic to aquatic life
GHS07 GENERAL PRECAUTIONARY STATEMENT If medical advice is needed, have product container or label at hand. Keep out of reach of children. Read label before use. P101+P102+P103 GHS PREVENTION STATEMENTS
P264 Wash affected areas thoroughly P280 Wear protective gloves/protective clothing/eye protection/face protection. P270 Do not eat, drink or smoke when using this product. GHS RESPONSE STATEMENTS P302+P352 IF ON SKIN: Wash with plenty of soap and water. P321 Specific treatment [See Section IV for Additional Information] P332+P313 If skin irritation occurs: Get medical advice/attention. P362 Take off contaminated clothing and wash before reuse. P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes remove contacts lenses, if present and easy to do. Continue rinsing. P337+P313 IF eye irritation persists: Get medical advice/attention. P301+P312 IF SWALLOWED: Call a POISON CENTER or doctor/physician if you feel unwell. P330 Rinse mouth. P304+P340 IF INHALED: Remove to fresh air and keep at rest in a position comfortable
HMIS CODE
Health Fire Reactivity Protection
1 0 0 B
0
NFPA CODE
1
Key to GHS Hazard Categories 1=Severe 2=Serious Hazard Hazard
0
3=Moderate Hazard
4=Slight Hazard
5=Minimal Hazard
The hazard level of this Substance or Mixture has been determined based on established data for components, internal testing, external testing of this or equivalent products, or a combination of these elements. FibroChem LLC makes no guarantee to the accuracy or completeness of any testing or statements from outside entities or organizations
III – COMPOSITION Classification : Mixture Components CAS 2475-46-9 Synonyms
Hazards Not hazardous Acetate Brilliant Blue 4B Acetoquinone Light Pure Blue R Altocyl Brilliant Blue B Amacel Blue BNN
% 80-95%
Amacel Brilliant Blue B 9,10-Anthracenedione 1-((2-hydroxyethyl)amino)-4-(methylamino)-(9CI) Artisil Blue BSQ Calcosyn Sapphire Blue 2GS Calcosyn Sapphire Blue R Celanthrene Brilliant Blue Celanthrene Brilliant Blue FFS Celliton Blue FFR Celliton Fast Blue FFRN Celliton Fast Blue FFRS Celutate Blue BLT Celutate Blue RNH Celutate Brilliant Blue B C.I. 61505 Cibacet Blue BNG Cibacet Blue F3R Cibacet Brilliant Blue BG New C.I. Disperse Blue 3 Cilla Fast Blue FFR Diacelliton Fast Brilliant Blue BF Disperse Blue K Disperse Blue 3 Dispersive Blue K Duranol Brilliant Blue B Duranol Brilliant Blue BN Duranol Printing Blue B Eastman Blue BNN Eastman Blue GBN Fenacet Fast Blue FF Fenacet Fast Blue FFN 4-Hydroxyethylamino-1-methylaminoanthraquinone Interchem Acetate Blue B Interchem Acetate Blue CONFIDENTIAL under applicable US laws and regulations. The formula will made available to qualified medical personnel in the event of an emergency. IV – FIRST AID MEASURES
Eyes
:
Hazard May cause irritation.
Skin
:
May cause irritation.
Inhalation
:
May cause irritation to the respiratory tract.
Ingestion
:
This product may be harmful if ingested. Do not ingest this product!
Effects of Overexposure
:
Not known.
First Aid Eyes
:
IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. IF eye irritation persists: Get medical advice/attention. (P305+P351+P338+P337+ P313).
Skin
:
IF ON SKIN: Wash with plenty of soap and water. If irritation occurs, get medical advice/attention. Take off contaminated clothing and wash before reuse. (H315 + P302+P352+P332+P323+P363)
Inhalation
:
Not expected to pose a respiratory hazard under normal conditions of use. IF INHALED: If breathing is difficult, remove to fresh air and keep at rest in a position comfortable for breathing. If breathing has stopped, immediately administer artificial respiration and seek medical attention. Call a POISON CENTER or doctor/ physician if you feel unwell. (P304+P312+P341)
Ingestion
:
IF INGESTED: Dilute with water. Do not induce vomiting. A PHYSICIAN SHOULD BE SEEN IMMEDIATELY IF THE PRODUCT IS INGESTED. Ingestion may cause gastrointestinal irritation, diarrhea, nausea, and vomiting. MAY BE HARMFUL IF SWALLOWED: Call a POISON CENTER or doctor/physician if you feel unwell. Rinse mouth. Keep victim warm and quiet. If victim is conscious give two glasses of water to dilute. Never give anything by mouth to an unconscious person. If victim is unconscious, lay on side and keep breathing passages clear (H303+P301+P312+P330+P321).
Comments
:
First aid responders should limit their direct contact with material. Use of impermeable gloves and protective eyewear in addition to protective equipment outlined in Section VII is recommended. The consumer assumes the liability to ensure that safe and proper procedures are followed in the use and handling of this product. It
is incumbent upon the consumer to ensure that personnel are not dangerously exposing eyes, skin, and respiratory systems to this product without proper safeguards. Most important symptoms/effects, acute and delayed Potential acute health effects Eye contact
:
Exposure to airborne concentrations above statutory or recommended exposure limits may cause irritation of the eyes.
Inhalation
:
Exposure to airborne concentrations above statutory or recommended exposure limits may cause irritation of the nose, throat and lungs. Exposure to decomposition products may cause a health hazard. Serious effects may be delayed following exposure.
Skin contact
:
May cause an allergic skin reaction.
Ingestion
:
No known significant effects or critical hazards.
Over-exposure signs/symptoms Eye contact
:
Skin contact
:
Ingestion
:
Indication of immediate medical attention and special treatment needed, if necessary Notes to physician
:
Protection of first-aiders
No specific treatment. Treat symptomatically. Call medical doctor or poison control center immediately if large quantities have been ingested.
: V – FIRE FIGHTING MEASURES
Flash Point: >100°C Flammable limits Upper : NA Lower : NA Self ignition: Product does not self-ignite
Danger of explosion: Product does not present an explosion hazard. Extinguishing Media: Suitable extinguishing media
:
Water, foam, dry chemical, carbon dioxide
Unsuitable extinguishing : media
None known.
Specific hazards arising from the chemical
:
No specific fire or explosion hazard.
Hazardous thermal decomposition products
:
Emits toxic fumes under fire conditions.
Special protective actions for fire-fighters
:
Promptly isolate the scene by removing all persons from the vicinity of the incident if there is a fire. No action shall be taken involving any personal risk or without suitable training. Water on hot liquid may cause violent frothing and spread the fire.
Special protective equipment for fire-fighters
:
Wear self-contained breathing apparatus operated in a positive-pressure mode when fighting any chemical fire.
Remark
:
Not explosive
Unusual Fire and Explosion Hazard
:
None known
VI – ACCIDENTAL RELEASE MEASURES Personal precautions, protective equipment and emergency procedures For non-emergency : No action shall be taken involving any personal risk or personnel without suitable training. Evacuate surrounding areas. Keep unnecessary and unprotected personnel from entering. Do not touch or walk through spilled material. Avoid breathing dust. Provide adequate ventilation. Wear appropriate respirator when ventilation is inadequate. Put on appropriate personal protective equipment. Wear self-contained breathing apparatus, rubber boots, and heavy rubber gloves.
For emergency responders :
Environmental precautions
Methods and materials for containment and cleaning up
If specialized clothing is required to deal with the spillage, take note of any information in Section 8 on suitable materials. See also the information in "For non-emergency personnel." :
:
Avoid dispersal of spilled material and runoff and contact with soil, waterways, drains and sewers. Inform the relevant authorities if the product has caused environmental pollution (sewers, waterways, soil or air). Move containers from spill area. Approach release from upwind. Prevent entry into sewers, water courses, basements or confined areas. Avoid dust generation. Avoid creating dusty conditions and prevent wind dispersal.
_X_ Stop Flow
_X_ Use Skin Protection (See Section VIII)
___ Incinerate under controlled conditions
___ Neutralize
_X_ Eliminate all sources of ignition or flame
___ Incinerate using after burner and scrubber
_X_ Absorb or scrape up material
___ Water wash spill residual
___ Bury in approved area
_X_ Avoid Breathing Fumes
___ Vacuum up
_X_ Use Respiratory PPE (See Section VIII)
_X_ Avoid Skin Contact
_X_ Remove Soiled Clothes
_X_ Prevent material from reaching storm drains
___ Evaporate small amount in Hood.
_X_ Observe Federal spill And Water regulations
_X_ Wash affected area Thoroughly after handing
_X_ Other: After spill is contained and the excess is absorbed onto an absorbent medium, dispose of in accordance with all applicable local, state, and federal regulations. Do not discharge undiluted industrial materials into waterways. VII – HANDLING AND STORAGE Precautions for safe handling: Protective measures :
Store dark at 5-8°C. Avoid extended exposure to sunlight. Put on appropriate personal equipment (see Section 8). Persons with a history of skin sensitization problems
should not be employed in any process in which this product is used. Do not get in eyes or on skin or clothing. Do not ingest. Avoid breathing dust. Keep in the original container or an approved alternative made from a compatible material, kept tightly closed when not in use. Empty containers retain product residue and can be hazardous. Do not reuse container. Advice on general occupational hygiene
:
Eating, drinking and smoking should be prohibited in areas where this material is handled, stored and processed. Workers should wash hands and face before eating, drinking and smoking. Remove contaminated clothing and protective equipment before entering eating areas. See also Section 8 for additional information on hygiene measures.
Conditions for safe storage : including any incompatibilities
Store in accordance with local regulations. Store in original container protected from direct sunlight in a cool, dry and well-ventilated area, away from incompatible materials (see Section 10) and food and drink. Keep container tightly closed and sealed until ready for use. Containers that have been opened must be carefully resealed and kept upright to prevent leakage. Do not store in unlabeled containers. Use appropriate containment to avoid environmental contamination. Keep away from heat, sparks, excessive moisture and open flames. Empty drums should not be cut with torches, grinders, or other heat-producing devices. without first thoroughly cleaning with water and ensuring that no dangerous vapors are present in the empty drum.
VIII – EXPOSURE CONTROLS / PERSONAL PROTECTION General Ventilation _X_
Local Exhaust _*_
Respiratory Protection _*_
_X_ - Recommended * Not usually required under normal handling conditions. Use NIOSH approved respirator if exposure levels are irritating or cause discomfort to personnel or if TLV or PEL of hazardous ingredients is approached. Control parameters
Appropriate engineering controls
:
Use only with adequate ventilation. If user operations generate dust, fumes, gas, vapor or mist, use process enclosures, local exhaust ventilation or other engineering controls to keep worker exposure to airborne contaminants below any recommended or statutory limits.
Environmental exposure controls
:
Emissions from ventilation or work process equipment should be checked to ensure they comply with the requirements of environmental protection legislation. In some cases, fume scrubbers, filters or engineering modifications to the process equipment will be necessary to reduce emissions to acceptable levels.
Individual protection measures Hygiene measures
:
Wash hands, forearms and face thoroughly after handling chemical products, before eating, smoking and using the lavatory and at the end of the working period. Appropriate techniques should be used to remove potentially contaminated clothing. Contaminated work clothing should not be allowed out of the workplace. Wash contaminated clothing before reusing. Ensure that eyewash stations and safety showers are close to the workstation location.
Eye/face protection
:
Safety eyewear complying with an approved standard should be used when a risk assessment indicates this is necessary to avoid exposure to liquid splashes, mists, gases or dusts. If contact is possible, the following protection should be worn, unless the assessment indicates a higher degree of protection: safety glasses with side-shields. If operating conditions cause high dust concentrations to be produced, use dust goggles.
Hand protection
:
Chemical-resistant, impervious gloves complying with an approved standard should be worn at all times when handling chemical products if a risk assessment indicates this is necessary. Considering the parameters specified by the glove manufacturer, check during use that the gloves are still retaining their protective properties. It should be noted that the time to breakthrough for any glove material may be different for different glove manufacturers. In the case of mixtures, consisting of several substances, the protection time of the gloves cannot be accurately estimated.
Body protection
:
Personal protective equipment for the body should be selected based on the task being performed and the risks involved and should be approved by a specialist before handling this product.
Other skin protection
:
Appropriate footwear and any additional skin protection measures should be selected based on the task being performed and the risks involved and should be approved by a specialist before handling this product.
Respiratory protection
:
Respirator selection must be based on known or anticipated exposure levels, the hazards of the product and the safe working limits of the selected respirator.
Thermal hazards
:
Not available.
Permissible Exposure Limits (PELs)
:
Not applicable
Threshold Limit Value (TLVs)
:
Not applicable
Eye Protection: Appropriate Safety Glasses or Goggles (Goggles are recommended for liquids, vapors or dusts)
Gloves: Use chemical resistant, rubber, or neoprene type
Other: Safety shower and eye wash station. Wash contaminated clothing before using again. Maintain proper hygeine controls. Wash hands after contact with material. Keep away from food and beverages.
IX – PHYSICAL AND CHEMICAL PROPERTIES Boiling Point Melting Point Freezing Point Upper Flammability Limit Auto Ignition Temperature Ignition temperature (°C) : SIT > 450 *ASTM-D1929B)
: : : : : :
ND ND ND ND ND Not applicable
Molecular weight
:
296.33 AMU
Formula
:
C17H16N2O3
Vapor Pressure (mm Hg) Vapor Density (Air = 1) Water Solubility: pH (100%) Partition coefficient: n-octanol/water Specific Gravity Flash Point (PMCC) Lower Flammability Limit Decomposition Temperature % Volatiles Evaporation Rate (ether=1): Refractive Index (@25ºC) Viscosity (@25ºC) Appearance and Odor
: : : : : : : : : : : : : :
ND >1 Insoluble ND ND ND NA ND ND ND >1 ND ND Solid black grey powder. Odor characteristic.
X – STABILITY AND REACTIVITY Stability:
_X_
Reactivity
:
No specific test data related to reactivity available for this product or its ingredients.
Chemical Stability
:
This product is stable.
Possibility of hazardous reactions
:
Under normal conditions of storage and use, hazardous reactions will not occur.
Conditions to Avoid
:
None known to cause hazardous instability. Store in a cool, dry location.
Stable
______
Unstable
Hazardous Decomposition Products
:
May produce fumes, smoke, oxides of carbon, hydrocarbons, nitrogen oxides, and inorganic oxides.
Incompatible Materials (Materials to Avoid)
:
No specific data.
Hazardous Polymerization: _________May occur
___XXX__Will not occur
XI – TOXICOLOGICAL INFORMATION Information on toxicological effects Acute toxicity Oral
:
Rat
1345 mg/kg LD50 Remarks: Behavioral: Somnolence (general depressed activity). Skin and Appendages: Skin: After systematic exposure: Dermatitis, other. Intraperitoneal
:
Rat 700 mg/kg LD50
Oral
:
Mouse 1600 mg/kg LD50 Remarks: Behavioral: Somnolence (general depressed activity). Kidney, Ureter, Bladder: Other changes in urine composition. Skin and appendages: Skin: After systematic exposure: Dermatitis, other.
Skin
:
Rabbit >2000 mg/kg LD50
Irritation/Corrosion Eyes
:
Rabbit 500 mg 24h Remarks: Mild irritation effect
Conclusion/Summery Skin
:
Mildly irritating with prolonged exposure.
Eyes
:
Mildly irritating with prolonged exposure.
Respiratory
:
No known significant effects or critical hazards
Sensitization
:
Not available
Carcinogenicity
:
Not available
Reproductive toxicity
:
Not available
Teratogenicity
:
Not available
Specific target organ toxicity (single exposure)
:
Not available
Aspiration Hazard
:
Not available
Information on the likely routes of exposure
:
Not available
Eye contact
:
Exposure to airborne concentrations above statutory or recommended exposure limits may cause irritation of the eyes.
Inhalation
:
Exposure to airborne concentrations above statutory or recommended exposure limits may cause irritation of the nose, throat and lungs. Exposure to decomposition products may cause a health hazard. Serious effects may be delayed following exposure.
Skin contact
:
May be irritating to the skin. In particularly sensitive or over-exposed people, may cause an allergic skin reaction.
Ingestion
:
No known significant effects or critical hazards.
Potential acute health effects
Symptoms related to the physical, chemical and toxicological characteristics Eye contact : Inhalation : Skin contact : Ingestion : Delayed and immediate effects and also chronic effects from short & long-term exposure Short term exposure Potential immediate effects Potential delayed effects
: :
No data No data
Long term exposure Potential immediate effects Potential delayed effects
: :
No data No data
Potential chronic health effects General
:
Repeated or prolonged inhalation of
dust/vapors may lead to chronic respiratory irritation. Once sensitized, a severe allergic reaction may occur when subsequently exposed to very low levels. Carcinogenicity
:
Mutagenicity
:
Teratogenicity
:
Developmental effects
:
Fertility effects
:
No known significant effects or critical hazards. No known significant effects or critical hazards. No known significant effects or critical hazards. No known significant effects or critical hazards. No known significant effects or critical hazards.
Numerical measures of toxicity Acute toxicity estimates Not available Other information
:
Not available.
Legend: CEIL: Ceiling Exposure Limit PEL: Permissible Exposure Limit REL: Recommended Exposure Limit STEL: Short Term Exposure Limit TLV: Threshold Limit Value TWA: Time-Weighted Average N/D: Not Determined WEEL: Workplace Environmental Exposure Level ACGIH: American Conference of Governmental Industrial Hygienists AIHA: American Industrial Hygiene Association NIOSH: National Institute for Occupational Safety and Health OSHA: Occupational Safety and Health Administration
XII – ECOLOGICAL INFORMATION Environmental Toxicity: None known beyond that described in prior and preceding sections
Conclusion/Summary
:
No further information available.
Conclusion/Summary
:
No further information available.
Bio-accumulative Potential
:
No further information available.
Mobility in Soil
:
No further information available.
Other adverse effects
:
No known significant effects or critical hazards
Other ecological information BOD COD TOC Organohalogen content Phosphorous content Nitrogen content Metal content HAP's VOC's
: : : : : : : : :
no data no data no data no data no data no data no data no data no data
Persistence and Degradability
XIII – DISPOSAL CONSIDERATIONS Disposal methods
:
The generation of waste should be avoided or minimized wherever possible. Disposal of this product, solutions and any by-products should at all times comply with the requirements of environmental protection and waste disposal legislation and any regional local authority requirements. Dispose of surplus and non-recyclable products via a licensed waste disposal contractor. Waste should not be disposed of untreated to the sewer unless fully compliant with the requirements of all authorities with jurisdiction. Waste packaging should be recycled. Incineration or landfill should only be considered when recycling is not feasible. This material and its container must be disposed of in a safe way. Care should be taken when handling emptied containers that have not been cleaned or rinsed out. Empty containers or liners may retain some product residues. Avoid dispersal of
spilled material and runoff and contact with soil, waterways, drains and sewers.
Disposal should be in accordance with applicable regional, national, and local laws and regulations. XIV – TRANSPORTATION INFORMATION DOT Hazardous Shipping Classification
:
Non-regulated material
IATA
:
Non-Hazardous for Air Transport
UN Number
:
N/A
UN Proper Shipping Name
:
N/A
Transportation Hazard Class
:
N/A
Packing Group
:
N/A
Environmental Hazard
:
N/A
IMDG
:
Not regulated
Marine Pollutant
:
No
Special Precautions
:
None other than those described above.
XV – REGULATORY INFORMATION United States Comprehensive Environmental Response, Compensation, and Liability Act (CERCLA) Not present or below 0.1 % (wt.) Superfund Amendments and Reauthorization Act (SARA): Title 40 CFR 372 (Protection of the Environment): No ingredients above De Minimis amounts. Section 302 (Extremely Hazardous Substances): Not listed
Section 311/312 (Hazard Class): Acute: No Chronic: No Fire: No Pressure: No Reactive: No Section 313 (Toxic Chemical Listings): None present or below De Minimis TSCA (Toxic Substance Control Act)
:
This product or its components, if a mixture, is listed in the TSCA Inventory of Chemical Substances.
TSCA 5(a)2 final significant new use rule (SNUR)
:
No ingredients listed.
TSCA 5(e) substance consent order
:
No ingredients listed.
TSCA 12(b) export notification
:
No ingredients listed.
Clean Air Act - Ozone Depleting Substances (ODS)
:
This product does not contain nor is it manufactured with ozone-depleting substances
California Proposition 65
:
This product contains no listed substances known to the State of California to cause cancer, birth defects or other reproductive harm, at levels which would require a warning under the statute.
PENNSYLVANIA - RTK
:
No ingredients listed.
Individual State Regulatory Information:
Carcinogenic Classifications IARC (International Agency for Research on Cancer): None of the components of this material are listed as carcinogens. NTP (National Toxicology Program): None of the components of this material are listed as carcinogens.
ACGIH (American Conference of Industrial Hygienists): None of the components of this material are listed as carcinogens.
International Regulatory Information European Union: European Inventory of Existing Chemical Substances (EINECS)
:
Indication of Danger: Harmful R: 22 R: 43 Risk Statements: Harmful if swallowed. May cause sensitization by skin contact. Symbol of Danger: Xn
Hazard Codes
:
Xn
Risk Statements
:
Harmful if swallowed. May cause sensitization by skin contact.
Safety Statements
:
Harmful
Brazil Regulations Classification system used
:
Norma ABNT-NBR 14725-2:2012
:
Not Listed
Canada Canadian Domestic Substances List (DSL)
WHMIS Classes : Not Listed This product has been classified in accordance with the hazard criteria of the Controlled Products Regulations and the SDS contains all the information required by the Controlled Products Regulations. CEPA DSL
:
Not Listed
Canadian Non-Domestic Substances List (NDSL)
:
Not Listed
XVI – OTHER INFORMATION References:
This SDS is compiled from one or more of the following: 1- SAX, Dangerous Properties of Industrial Materials
2- NIOSH, Pocket Guide to Chemical Hazards 3- ACGIH, Threshold Limit Values and Biological Exposure Indices 4- Safety Data Sheets of component Materials Legend:
NA= Not Applicable > = Greater Than
ND= Not Determined NE= Not Established
< = Less than
The information and recommendations presented herein are presented in good faith and are believed to be correct as of the date hereof and are not intended to infringe upon any patents and/or patents pending. Fibro Chem, LLC makes no representations as to the completeness or accuracy thereof. Information is supplied upon the conditions that the persons receiving the information will make their own determinations as to its suitability for their purposes prior to use. In no event will Fibro Chem, LLC be responsible for damages of any nature whatsoever resulting from the use of, or reliance upon, this information. NO REPRESENTATIONS OR WARRANTIES, EXPRESSED OR IMPLIED, OF MERCHANTABILITY, FITNESS FOR A PARTICULAR PURPOSE, OR OF ANY OTHER NATURE ARE MADE HEREUNDER WITH RESPECT TO INFORMATION OR THE PRODUCT TO WHICH THE INFORMATION REFERS. This form meets the requirements of OSHA 29 CFR 1910.1200.R212
