Mochras core Cardigan Bay Basin, Wales, UK

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Hand-held XRF standard analyses. Hand-held XRF internally calibrated uncertainty for analysed samples. Calculated uncertainty is based on the combined.
Mochras core Cardigan Bay Basin, Wales, UK δ13CTOC[‰] -29

-27

-25

-23 1.0

1.5

2.0

Zr/Rb

2.5

3.0

3.5

630

660

JF15

2.0

2.2

2.4

830

780 790

Ti/Al

δ13CTOC[‰] 0.04 600

610

610

620

620

630

630

640

640

650

650

660

660

670

670

680

680

690

690

700

700

710

710

720

720

730

730

740

740

750

750

760

760

770

770

780

780

790

790

800

800 810

T-OAE negative CIE

820 830 840 850 860 870

δ13CTOC[‰] -29

-27

-25

-23 600

610

610

620

620

630

630

640

640

650

650

660

660

670

670

680

680

690

690

700

700

710

710

720

720

730

730

740

740

750

750

760

760

770

770

780

780

790

790

800

800

JF12b

850

JF12a

870

860

Strat. pos. [mbs]

820 840

0.12

0.045

T-OAE negative CIE

840 850 860 870

0.065

0.075

0.085

0.045

0.055

0.065

0.075

0.050

0.055

0.060

0.065

0.070

0.075

800

810

820

830

840

850

860

Si/Al 2.8

3.8

Si/Al 4.8

5.8

1.8

6.8

2.2

2.6

3.0

Si/Al [5-point mov. average] 3.4

3.8

1.8

2.2

2.6

3.0

3.4

Si/Al [15-point mov. average] 2.0

2.2

2.4

2.6

2.8

3.0

780

790

800

810

820

830

840

820 830

0.055

790

810

810 830

0.10

780

1.8

600

0.08

850 Strat. pos. [mbs]

JF12b

860

Strat. pos. [mbs]

820

0.06

Stratigraphic position [mbs]

-23

Ti/Al [15-point mov. average]

860

Stratigraphic position [mbs]

-25

Ti/Al [5-point mov. average]

Stratigraphic position [mbs]

-27

Ti/Al

Stratigraphic position [mbs]

-29

600

830

860

Stratigraphic position [mbs]

870

860

850

Stratigraphic position [mbs]

850

Strat. pos. [mbs]

830

Strat. pos. [mbs]

T-OAE negative CIE

820

Stratigraphic position [mbs]

Stratigraphic position [mbs]

810

Stratigraphic position [mbs]

840

800

Stratigraphic position [mbs]

variabilis bifrons

com. fibul. crass. JF14

falciferum

1.8

770

JF13

exaratum

1.6

820

760

JF12b

spinatum JF16 JF15 JF14 JF13

2.6 1.4

750

JF12a JF16 JF15 JF14

2.4

740

870

JF13

2.2

710

JF12a

TOARCIAN

tenuicostat.

serpentinum

LOWER JURASSIC

PLIENSB.

levesquei pseudo. fa. fallac.

thouars. dis. pseudoradiosa aal. bifrons

variabilis levesquei pseudo.

2.0

810

700

730

850

fa. fallac.

1.8

680

810

com. fibul. crass. falciferum exaratum

1.6

800

670

840

com. fibul. crass. falciferum exaratum

TOARCIAN

tenuicostat. spinatum thouars. dis. pseudoradiosa aal.

1.4

650

840

variabilis bifrons serpentinum tenuicostat. spinatum

3.0 1.2

790

720

serpentinum

LOWER JURASSIC

PLIENSB.

2.5

640

-31

TOARCIAN

2.0

620

-31

LOWER JURASSIC

1.5

Zr/Rb [15-point mov. average]

780

690

PLIENSB.

1.0

Zr/Rb [5-point mov. average]

610 JF16

levesquei pseudo.

600

fa. fallac.

thouars. dis. pseudoradiosa aal.

-31

Zr/Rb

Hand-held XRF standard analyses

Calculated uncertainty is based on the combined HH-XRF internally calibrated uncertainty on sample analyses, and the uncertainty (1-St. Dev.) on multiple standard measurements. Standard deviation (1-St. Dev.) on multiple samples in selected stratigraphic intervals. Standard deviation (1-St. Dev.) on the positive and negative envelopes of the calculated uncertainty (grey-shaded area), for selected stratigraphic intervals.

Si [%] Ti [ppm] Rb [ppm] Zr [ppm] Al [%]

NIST 2711 - A NIST 2711 - A NIST 2711 - A NIST 2710 - A NIST 2710 - A

(n = 38) (n = 38) (n = 38) (n = 33) (n = 33)

Measured Average 17.44 3053 114.0 220.0 5.41

STDEV 0.29 81 1.0 3.7 0.12

Hand-held XRF internally calibrated uncertainty for analysed samples HH-XRF Internal calibrated uncertainty Si 0.04–0.08 Ti 0.007–0.009 Rb 0.0001 Zr 0.0001–0.0002 Al 0.05–0.07

3.2

3.4