MSDS dated Friday, December 02, 2011 - KellySolutions.com

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18 Nov 2011 ... Material Safety Data Sheet. CONTRAM(TM) ST-1. Prepared according to 29CFR 1910.1200. 1. Chemical Product and Company Identification.
CONTRAM(TM) ST-1 Material Safety Data Sheet CONTRAM(TM) ST-1

Prepared according to 29CFR 1910.1200. 1

Chemical Product and Company Identification The Lubrizol Corporation 29400 Lakeland Boulevard Wickliffe, Ohio 44092 Tel: (440) 943-4200

Product Trade Name CAS Number Synonyms Generic Chemical Name Product Type Preparation/Revision Date Transportation Emergency Phone No. MSDS No. 2

CONTRAM(TM) ST-1 5625-90-1 None. N,N-methylenebismorpholine Metalworking fluid additive. Metalworking Biocides 18 November 2011 FOR TRANSPORT EMERGENCY call CHEMTREC: (+1) 703-527-3887 (outside the U.S.), 1-800-424-9300 (in the U.S.) 21304947-1417111-113121-102103 Hazards Identification

Appearance Odor Principal Hazards

Yellow liquid. Strong Danger. l Causes eye burns. l Causes skin burns. l May be harmful if swallowed. l May cause respiratory tract irritation.

See Section 11 for complete health hazard information. 3

Composition/Information on Ingredients

Hazardous Ingredients Comp

CAS No. 5625-90-1

N,N-methylenebismorpholine

Percentage (by wt.) From 90 to 100 percent

Carcinogen N/E

(N/E) - None established 4 Eyes Skin Inhalation Oral Additional Information 5 Flash Point Extinguishing Media Firefighting Procedures Unusual Fire & Explosion Hazards

First Aid Measures Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Immediately call a poison center or doctor. Immediately remove all contaminated clothing. Rinse skin with water / shower. Immediately call a poison center or doctor. Launder contaminated clothing before reuse. Remove victim to fresh air and keep at rest in a position comfortable for breathing. Immediately call a poison center or doctor. Do NOT induce vomiting. Rinse mouth. Immediately call a poison center or doctor. If exposed or concerned: Get medical attention. Fire Fighting Measures > 120 °C, 248 °F PMCC (Minimum) CO2, dry chemical, or foam. Water can be used to cool and protect exposed material. Recommend wearing self-contained breathing apparatus. Water may cause splattering. Use water to cool containers exposed to fire. See section 10 for additional information.

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CONTRAM(TM) ST-1 6 Spill Procedures

7 Pumping Temperature Maximum Handling Temperature Handling Procedures

Maximum Storage Temperature Storage Procedures Maximum Loading Temperature 8 Exposure Limits Other Exposure Limits Engineering Controls Gloves Procedures Eye Protection Respiratory Protection Clothing Recommendation

9 Flash Point Upper Flammable Limit Lower Flammable Limit Autoignition Point Explosion Data Vapor Pressure pH Specific Gravity Bulk Density Water Solubility Percent Solid Percent Volatile Volatile Organic Compound Vapor Density Evaporation Rate Odor Appearance Viscosity Odor Threshold Boiling Point Pour Point Temperature Melting / Freezing Point

Accidental Release Measures Personal Protective Equipment must be worn, see Personal Protection Section for PPE recommendations. Take precautions to avoid release to the environment. Ventilate area if spilled in confined space or other poorly ventilated areas. Prevent entry into sewers and waterways, dispose of in accordance with all federal, state and local environmental regulation. Pick up free liquid for recycle and/or disposal. Residual liquid can be absorbed on inert material. Handling and Storage 40 °C, 104 °F 60 °C, 140 °F Keep containers closed when not in use. Do not discharge into drains or the environment, dispose to an authorized waste collection point. Use appropriate containment to avoid environmental contamination. Do not breathe dust or mist. Wash thoroughly after handling. Launder contaminated clothing before reuse. Empty container contains product residue which may exhibit hazards of product. Do not eat, drink or smoke when using this product. Dispose of packaging or containers in accordance with local, regional, national and international regulations. 40 °C, 104 °F Take precautions to avoid release to the environment. Store locked up. See section 10 for incompatible materials. Not determined. Exposure Controls/Personal Protection None established None known. Use material in well ventilated area only. Additional ventilation or exhaust may be required to maintain air concentrations below recommended exposure limits. Use nitrile or neoprene gloves. Chemical goggles or faceshield. Under normal use conditions, respirator is not usually required. Gloves, coveralls, apron, boots as necessary to minimize contact. Wear either a chemical protective suit or apron when potential for contact with material exists. Use chemically protective boots when necessary to avoid contaminating shoes. Do not wear rings, watches or similar apparel that could entrap the material and cause a burn. Launder contaminated clothing before reuse. Physical and Chemical Properties > 120 °C, 248 °F PMCC (Minimum) Not determined. Not determined. Not determined. Material does not have explosive properties. 0.041 mBars (25 °C) 10.5 1.05 (20 °C) Not determined. Dispersible. Not determined. Not determined. Not determined. Not determined. Not determined. Strong Yellow liquid. 16 Centistokes (20 °C) Not determined. 266 °C, 510.8 °F(Typical) Not determined. Not determined. The above data are typical values and do not constitute a specification. Vapor pressure data are calculated unless otherwise noted.

10 Stability

Stability and Reactivity Material is normally stable at moderately elevated temperatures and pressures. This product may crystallize below 15°C. If

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CONTRAM(TM) ST-1 Decomposition Temperature Incompatibility Polymerization Thermal Decomposition Conditions to Avoid 11

Eye Irritation Skin Irritation Respiratory Irritation Dermal Toxicity Inhalation Toxicity Oral Toxicity Dermal Sensitization Inhalation Sensitization

this occurs heating the product in a suitable heating chamber (up to a maximum of 50°C) will not affect the quality of the product. Not determined. Acids. Oxidizing agents. This material contains amine. Do not add nitrite or other nitrosating agents due to the potential for nitrosamine formation. Will not occur. Smoke, carbon monoxide, carbon dioxide, aldehydes and other products of incomplete combustion. Under combustion conditions, oxides of the following elements will be formed: nitrogen. Formaldehyde vapor may also be released. Not determined. Toxicological Information

-- ACUTE EXPOSURE -Corrosive to eyes. Based on data from components or similar materials. Corrosive to the skin. Based on actual data. May cause nose, throat, and lung irritation. Based on data from components or similar materials. The dermal toxicity potential of this substance is not completely understood. Avoid handling and use practices that could result in prolonged or repeated skin exposure. No data available to indicate product or components may be a toxic inhalation hazard. The LD50 in rats is 500 – 2000 mg/Kg. Based on actual data. Swallowing this material causes severe irritation and may cause burns of the mouth, esophagus and stomach, abdominal pain, nausea, vomiting and diarrhea. Not expected to cause skin sensitization. Based on actual data. No data available to indicate product or components may be respiratory sensitizers.

Teratogenicity

-- CHRONIC EXPOSURE -No data available to indicate product or components present at greater than 1% are chronic health hazards. Not listed as a carcinogen or suspect carcinogen by NTP, IARC or OSHA. N,N-methylenebismorpholine tested positive for mutagenicity and clastogenicity in bacterial and mammalian cell in vitro assays but was negative for genotoxicity in mouse micronucleus and rat hepatocyte UDS in vivo assays. No data available to indicate either product or components present at greater than 0.1% that may cause reproductive toxicity. No data available to indicate product or any components contained at greater than 0.1% may cause birth defects.

Other

-- ADDITIONAL INFORMATION -No other health hazards known.

Chronic Toxicity Carcinogenicity Mutagenicity Reproductive Toxicity

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Freshwater Fish Toxicity Freshwater Invertebrates Toxicity Algal Inhibition Saltwater Fish Toxicity Saltwater Invertebrates Toxicity Bacteria Toxicity Miscellaneous Toxicity

Biodegradation Bioaccumulation Soil Mobility 13 Waste Disposal

14 ICAO/IATA I ICAO/IATA II IMDG

Ecological Information

-- ENVIRONMENTAL TOXICITY -The acute LC50 is 100 - 1000 mg/L based on actual data. The acute EC50 is 10 - 100 mg/L based on actual data. The acute EC50 is 1 - 10 mg/L based on actual data. Not determined. Not determined. The acute EC50 is 100 - 1000 ppm based on actual data. Not determined. -- ENVIRONMENTAL FATE -This product will biodegrade very rapidly based on OECD 301-type test data for similar products. Meets ready biodegradation criteria. This material displays no potential to bioconcentrate. Not determined. Disposal Considerations This material, if discarded, is not a hazardous waste under RCRA Regulation 40 CFR 261. Treatment, storage, transportation, and disposal must be in accordance with applicable Federal, State/Provincial, and Local regulations. Transport Information UN3267 Corrosive liquid, basic, organic, n.o.s. (N,N-methylenebismorpholine) , 8 , III UN3267 Corrosive liquid, basic, organic, n.o.s. (N,N-methylenebismorpholine) , 8 , III UN3267 Corrosive liquid, basic, organic, n.o.s. (N,N-methylenebismorpholine) , 8 , III

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CONTRAM(TM) ST-1 IMDG EMS Fire IMDG EMS Spill IMDG MFAG MARPOL Annex II USCG Compatibility U.S. DOT Bulk DOT NAERG U.S. DOT (Intermediate) U.S. DOT Intermediate NAERG U.S. DOT Non-Bulk U.S. DOT Non-Bulk NAERG Canada Mexico Bulk Quantity Intermediate Quantity Non-Bulk Quantity

F-A S-B 760 Not determined. Not determined. UN3267 Corrosive liquid, basic, organic, n.o.s. (N,N-methylenebismorpholine) 8 , III 153 UN3267 Corrosive liquid, basic, organic, n.o.s. (N,N-methylenebismorpholine) 8 , III 153 UN3267 Corrosive liquid, basic, organic, n.o.s. (N,N-methylenebismorpholine) 8 , III 153 UN3267 Corrosive liquid, basic, organic, n.o.s. (N,N-methylenebismorpholine), 8 , III UN3267 Corrosive liquid, basic, organic, n.o.s. (N,N-methylenebismorpholine) , 8 , III 85000 KG, 187391 lbs. 11000 KG, 24251 lbs. 400 KG, 882 lbs. Review classification requirements before shipping materials at elevated temperatures.

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USA

Other TSCA Reg. EU Japan Australia New Zealand Canada Switzerland Korea Philippines China Taiwan

SARA Ext. Haz. Subst. SARA Section 313

Regulatory Information

-- Global Chemical Inventories -This product is a registered pesticide regulated under the Federal Insecticide, Fungicide and Rodenticide Act (FIFRA). It may only be used in accordance with the provisions of the EPA approved product label in States that it is registered. This product may not be used for other applications since it is not on the TSCA inventory. None known. All components are in compliance with the EC Seventh amendment Directive 92 /32/EEC. All components are in compliance with the Chemical Substances Control Law of Japan. All components are in compliance with chemical notification requirements in Australia. All components are in compliance with chemical notification requirements in New Zealand. This product requires notification before sale in Canada. All components are in compliance with the Environmentally Hazardous Substances Ordinance in Switzerland. All components are in compliance in Korea. All components are in compliance with the Philippines Toxic Substances and Hazardous and Nuclear Wastes Control Act of 1990 (R.A. 6969). All components of this product are listed on the Inventory of Existing Chemical Substances in China. All components of this product are listed on the Taiwan inventory. -- Other U.S. Federal Regulations -This product does not contain greater than 1.0% of any chemical substance on the SARA Extremely Hazardous Substances list. This product does not contain greater than 1.0% (greater than 0.1% for carcinogenic substance) of any chemical substances listed under SARA Section 313.

SARA 311 Classifications

Acute Hazard Chronic Hazard Fire Hazard Reactivity Hazard

CERCLA Hazardous Substances

None known.

Cal. Prop. 65

-- State Regulations -This product does not intentionally contain any chemicals known by the State of California to cause cancer and/or birth defects. Moreover, we do not routinely analyze its products for impurities which may be such chemicals.

U.S. Fuel Registration Finnish Registration Number Swedish Registration Number Norwegian Registration Number Danish Registration Number Swiss Registration Number Italian Registration Number

Not applicable. Not Registered 488734-5 Not Registered Not Registered 611463 Not Registered

Yes No No No

-- Product Registrations --

-- Other / International --

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CONTRAM(TM) ST-1 Miscellaneous Regulatory Information 16 US NFPA Codes

HMIS Codes

Not determined.

Other Information Health Fire 3 1 (N/E) - None established Health 3

Reactivity 0

Fire 1

Precautionary Labels

Danger. l Causes eye burns. l Causes skin burns. l May be harmful if swallowed. l May cause respiratory tract irritation.

Revision Indicators

Section: 7 Storage procedures. Section: 15 U.S. TSCA inventory.

Special N/E

Reactivity 0

Changed: 27 February 2011 Changed: 8 November 2011

As the conditions or methods of use are beyond our control, we do not assume any responsibility and expressly disclaim any liability for any use of this product. Information contained herein is believed to be true and accurate but all statements or suggestions are made without warranty, expressed or implied, regarding accuracy of the information, the hazards connected with the use of the material or the results to be obtained from the use thereof. Compliance with all applicable federal, state, and local regulations remains the responsibility of the user.

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