Supporting Information - molybdenum-vanadium-antimony mixed oxide catalyst for isobutane partial oxidation synthesized using magneto hydrodynamic forces Bernard Stuyven§, Jens Emmerich§, Pierre EloyϮ, Jan Van Humbeeck#, Christine E.A. Kirschhock§, Pierre A. Jacobs§, Johan A. Martens§,*, Eric Breynaert§ Ϯ
Institute of Condensed Matter and Nanosciences (IMCN), BSMA - Croix du Sud 1 bte
L7.04.01, B-1348 Louvain-la-Neuve, Belgium #
Surface and Interface Engineered Materials, Department of Metallurgy and Materials
Engineering (MTM), KU Leuven, Kasteelpark Arenberg 44, box 2450, B-3001 Heverlee, Belgium §
KU Leuven Centre for Surface Chemistry and Catalysis, Kasteelpark Arenberg 23, box 2461,
B-3001 Heverlee, Belgium * Corresponding author – Tel: +3216321637 – Fax: +3216321998 – e-mail:
[email protected] http://dx.doi.org/10.1016/j.apcata.2013.07.039
Contribution in honor of Professor Bernard Delmon at the occasion of this 80th birthday.
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Figure S 1: XRD patterns of untreated senarmontite powder (a) and samples recirculated for 30 min through the (magneto-) hydrodynamic device at 5 L/min in absence (b) and in presence of the magnetic field (c).
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Figure S 2: Methacrolein (MAL), COx and isobutene selectivity vs. isobutane conversion in the partial oxidation of isobutane. Mo8V2Sb90Ox catalysts were synthesized with slurry type method (a,▪▪▪) and with MHD pretreatment, by recirculation of the precursors for 30 min at 5 L/min in presence of magnetic field (0.33 T) (b,▬). Two samples were analyzed for each catalyst at each temperature: (1) 350 °C, (2) 375 °C, (3) 400 °C, (4) 425 °C, (5) 450 °C.
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Figure S 3: Methacrolein (MAL) selectivity vs. isobutane conversion in the partial oxidation of isobutane. Mo8V2Sb90Ox catalyst was synthesized using magnetic field. Three consecutive runs were performed (a, b and c). Two samples were analyzed for each catalyst at each temperature: (1) 350 °C, (2) 375 °C, (3) 400 °C, (4) 425 °C, (5) 450 °C.
Figure S 4: XRD patterns of Mo8V2Sb90Ox catalysts synthesized by circulation of the precursors in presence of a magnetic field (0.33 T) (a) and in absence of the field (b). XRD measured in capillary mode (0.2 mm).
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Figure S 5: Methacrolein (MAL), COx and isobutene selectivity vs. isobutane conversion in the partial oxidation of isobutane. Mo8V2Sb90Ox catalysts were synthesized with slurry type method (a,▪▪▪) and with MHD pretreatment, by recirculation of the precursors for 30 min at 5 L/min in presence of magnetic field (0.33 T) (b,▬). Two samples were analyzed for each catalyst at each temperature: (1) 350 °C, (2) 375 °C, (3) 400 °C, (4) 425 °C, (5) 450 °C.
Figure S6: COx yield versus temperature for three different MHD synthesized Mo8V2Sb90Ox samples used throughout this study. The product stream was sampled twice at each temperature.