Offers excellent adhesion, early block resistance, and high binder efficiency. .....
Acrylic polyol for high solids polyurethane coatings with VOC exempt* solvent, ...
U.S. and Canada BASF Corporation Resins 1609 Biddle Avenue Wyandotte, MI 48192 Phone: +800-231-7868 Fax: +800-392-7429 e-mail:
[email protected] internet: www.basf.com/naftaresins Mexico BASF Mexicana, S.A. de C.V. Av. Insurgentes Sur 975 Col. Ciudad de los Deportes 03710 Mexico, D.F. Phone: +52-55-5325-2787 +52-55-5325-2687 Fax: +52-55-5611-4897
T h e s t a t e m e n t s i n t h e p ro d u c t l i t e r a t u re a n d l a b e l a re g u i d e l i n e s o n l y. U s e r s s h o u l d t e s t t h i s p ro d u c t i n a d v a n c e t o v e r i f y s u i t a b i l i t y f o r particular uses. BASF Corporation neither makes nor authorizes to be m a d e a n y e x p re s s o r i m p l i e d re p re s e n t a t i o n o r w a r r a n t y w i t h re g a rd t o t h i s p ro d u c t c o n c e r n i n g t h e p e r f o r m a n c e , u s e , f i t n e s s f o r p a r t i c u l a r p u r p o s e , s u i t a b i l i t y f o r u s e o n a n y s u r f a c e o r m e rc h a n t a b i l i t y o f t h i s p ro d u c t , w h e t h e r u s e d a l o n e o r i n c o m b i n a t i o n w i t h o t h e r p ro d u c t s . T h e f u r n i s h i n g b y u s o f i n f o r m a t i o n a n d p ro d u c t s e i t h e r a s e x p e r i m e n t a l s a m p l e s o r b y s a l e s , c o n t a i n s n o re c o m m e n d a t i o n s re s p e c t i n g t h e u s e o f t h e s e p ro d u c t s o r t h e l a c k o f i n f r i n g e m e n t o f a n y p a t e n t n o r d o e s i t g r a n t a l i c e n s e u n d e r a n y p a t e n t o w n e d b y o u r c o m p a n y. B A S F a s s u m e s n o l i a b i l i t y f o r a n y d a m a g e o f a n y k i n d re g a rd l e s s o f c a u s e , including negligence. A c ro n a l ® , B a s o n a t ® , C h i m a s s o r b ® , D a ro c u r ® , I r g a c u re ® , J o n c r y l ® , L a ro f l e x ® , L a ro p a l ® , L a ro m e r ® , L i g n o s t a b ® , L u c i r i n ® , L u h y d r a n ® , L u t o n a l ® , L u w i p a l ® , P l a s t o p a l ® , S o l v e n o n ® , a n d T i n u v i n ® a re re g i s t e re d t r a d e m a r k s of BASF Corporation. S o l v e s s o ® i s a re g i s t e re d t r a d e m a r k o f E x x o n M o b i l e C o r p o r a t i o n . © 2 0 1 0 B A S F, W y a n d o t t e , M I 4 8 1 9 2 . A l l r i g h t s re s e r v e d . CO Sel Gd v3.0-03/29/10.
A World of Reasons to Choose BASF
Table of Contents
Waterborne Systems Joncryl ® Acrylic Emulsions
page 4
Acronal ®, Joncryl, and Luhydran ® Self-crosslinking Acrylic Emulsions
page 6
Solventborne Systems Acronal Acrylic Resins
page 8
Lutonal ® Polyvinylether Resins
page 8
Joncryl Acrylic Polyols
page 10
Joncryl Rapid Property Polyols
page 12
Joncryl Fast-cure Acrylic Polyols
page 12
Laroflex Vinyl Chloride Binders
page 14
®
Broad Technolog y Portfolio At BASF, we focus on your needs and offer a depth and breadth of technology knowledge. Our cross-functional teams have extensive expertise in coatings chemistries, such as: Acr ylic, Aldehyde, Amino, and Polyester resins Additives Energy curing resins and photoinitiators Light stabilizers Polyisocyanates
Specialty Resins Laropal ® Aldehyde Resins for Pigment Dispersions
page 14
Joncryl Acrylic Resins for Pigment Dispersions
page 16
Joncryl Liquid Acrylic Flexiblizers for Solventborne Coatings
page 17
Additives Joncryl Additives for Waterborne Coatings
page 16
Chimassorb ®, Lignostab ®, Tinuvin ®, and Xymara TM CarboProtect TM Light Stabilizers
page 18
Crosslinkers Luwipal ® and Plastopal ® Amino Resins
page 20
Basonat Aliphatic Polyisocyanates
page 20
®
BASF, Your Supplier of Choice As the world’s leading chemical company, BASF is committed to you, our customers, by providing a sustainable enterprise, broad technology portfolio, unique performance attributes, and various ser vice capabilities. At BASF, we want to be your supplier of choice for the industrial coatings industr y. Please contact our Technical Ser vice Department for specific formulation challenges.
Energy Curable Systems Laromer ® Oligomers
page 22
Laromer Reactive Diluents
page 24
Darocur ®, Irgacure ®, and Lucirin ® Photoinitiators
page 25
Acrylic Powder Coating Resins Joncryl Acrylic Powder Resins
2
page 26
Sustainable Enterprise At BASF, sustainable enterprise means combining economic success with environmental protection and social responsibility, thus contributing to a future for generations to come. Our goal is to design products that help the coatings industr y preser ve the environment without sacrificing product performance.
Unique Performance Attributes At BASF, we know and understand the performance challenges you face with your customers. That is why we develop innovative solutions that address a multitude of performance attributes, such as: Chemical resistance Corrosion resistance Gloss Low VOC Weatherability
Ser vice Ca pabilities At BASF, we are committed to the industrial coatings industr y, and are focused on helping customers be more successful. We can help you be innovative and deliver quality products to your customers by offering various ser vices, such as: Formulation support Global R & D platform and manufacturing network Regulator y support
3
Joncryl® Acrylic Emulsions for Waterborne Industrial Coatings Solids (wt. %)
Viscosity (cps)
Glass Transition Temp. (Tg °C)
MFFT (°C)
pH
Acid No. (on solids)
Supplied Density (g/cm3)
FreezeTha w Stable
Pigment Grind Vehicle
Joncr yl 95
30
100
43
20
8.0
70
1.04
Yes
No
Ultra-fine particle size, colloidal dispersion for wood penetra tion and in-can clarity. Demonstra tes minimal grain raising, excellent sandability, and sealing characteristics. For use in stains, sealers, and wood preser va tives. Fea tures high Tg/lo w MFFT balance.
Joncr yl 530
49
700
75
95
8.5
50
1.04
Yes
Yes
A high Tg emulsion with good wa ter, humidity, and household chemical resistance. Suggested for hardboard, other wood coa tings, and general metal finishes.
Joncr yl 537
46
150
44
42
9.0
40
1.05
Yes
Yes
A “workhorse” emulsion with excellent gloss, clarity, adhesion, and manufacturing ease. Suitable as a sole vehicle or alkyd modifier for a variety of general metal, wood, and plastic finishes. Modifier for acr ylic and vin yl acr ylic architectural paints.
Joncr yl 538
45
200
64
65
9.3
53
1.07
Yes
Yes
A multipurpose acrylic emulsion featuring acid, gasoline, and MEK resistance. Suggested for wood flat-stock primers and topcoats and as a modifier to improve hardness and solvent resistance.
Joncr yl 540
44
500
-
70
8.3
55
1.04
Yes
Yes
A ver y hard emulsion often used as a blend vehicle to impart hardness and block resistance. Suitable for wood finishes and hardboard primers.
Joncr yl 1915
44
800
43
60
8.5
17
1.03
No
No
Emulsion for ambient or force-dr y cure systems offering good chemical resistance. Ideal for wood, concrete, and plastics a pplica tions.
Joncr yl 1993
43
90
22
17
8.4
17
1.03
No
No
Emulsion with good water resistance and adhesion for wood applications. Lower VOC product compared to Joncryl 1992 with the same application and performance properties.
Joncr yl 2561
48
750
- 11
70
8.4
17
1.03
S e l f - c r o s s l i n k i n g e m u l s i o n w i t h f o r m u l a t i o n s t a b i l i t y, e x h i b i t i n g U V r e s i s t a n c e , a n d f i l m hardness. Recommended for concrete and wood applications.
Joncr yl 1987
-
42
200
14
12
8.5
16
1.03
One-pack, self-crosslinking emulsion with good chemical resistance, excellent adhesion, and water resistance. Lower VOC requirements to meet regulations while maintaining enhanced performance.
Joncr yl 8383
-
40
95
14
16
8.2
23
1.05
Soft, self-crosslinking emulsion offering good clarity and "warmth of wood"; good chemical and block resistance with excellent water resistance and wet adhesion. Recommended for concrete and wood applications.
Luhydran A 848 S
Butyl Methacr yla te
44.5 ± 1
150 - 250
-
39
6.5 - 7.5
-
1.05
H i g h s t a n d a r d d i s p e r s i o n f o r j o i n e r y, i n d u s t r i a l w o o d , a n d c o n c r e t e a p p l i c a t i o n s . G o o d chemical and mechanical resistance.
Luhydran N 850 S
n-Butyl Acr yla te/ Acr ylonitrile
40 - 42
10 - 50
-
25
7-8
-
1.03
Self-crosslinking emulsion with good chemical and mechanical resistant properties. Suitable for parquet flooring.
Luhydran A 875 S
Methacr ylic
43 - 46
20 - 100
-
60
6.5 - 7.5
-
1.04
Flexible version of Luhydran N 850 S.
Luhydran S 938 T
Hydroxylic Acr ylic/ Methacr ylic/Styrene
45
25
-
60
2
-
1.06
APEO-free crosslinkable emulsion for furniture oils or heat-cure coatings and twocomponent polyurethane interior applications. Hydroxyl value of 100.
Product
Acronal PRO 761
6
Description and A pplica tions
7
Acronal® Acrylic Resins for Solventborne Industrial Coatings Product
Type of Resin
Physical Form
Solids (wt. %)
Viscosity (cps)
Acid Value (mg KOH/g)
Density (g/cm 3 )
Iodine Color Number
Flash Point (°C)
Surface Tension (mNm-1)
Glass Transition Temp. (Tg °C)
Liquid
> 98.5
600,000 700,000
-
1.05
0 - 1
150
-
- 40
Solubility
Compa tibility
Description and A pplica tions
Acronal acr ylic resins are used, particularly in Acronal 4 F
Cellulose Nitra te,
Acronal 700 L
pa per and film coa tings, sealing wax, coa tings
Glycol Ethers,
Acronal 4 L
49.0 - 51.0
Copolymer of n-Butyl Acr yla te and Vin yl Isobutyl Ether
combina tion with cellulose nitra te, for formula ting Esters,
Poly n-Butyl Acr yla te 1,600 - 2,600
-
0.97
0 - 1
150
-
- 40
Vin yl Chloride
lacquers. Combined with chlorina ted binders
Polymers,
Solution in Ethyl Aceta te
for light metals and plastics, and cellulose
Ketones, Aroma tic and
50 ± 1
500 - 800
1
0.96
0 - 1
- 4
-
-
Poly acr yla tes,
such as Laroflex ® MP grades, they yield coa tings
Na tural Resins,
tha t are ver y resistant to hydrolysis for various
Chlorina ted Hydrocarbons, Plasticizers
substra tes such as metals, concrete, or fiber
Mineral Spirits Acronal LR 8820
Poly n-Butyl Acr yla te
Colorless Clear Liquid
> 98.5
20,000 - 50,000
90
2,500 - 6,000
-
0.96
Iodine Color Number
15
Flash Point (°C)
K Value
Glass Transition Temp. (Tg °C)
63
10 - 17
- 43
Polyvin yl Ethyl
Alcohols, Esters, Ketones; Alipha tic, Aroma tic and Chlorina ted Hydrocarbons
Lutonal A 50
Solution in Ethanol
50 ± 2
5,000 - 20,000
-
0.87
4
9
55 - 65
- 30
Lutonal M 40 50% H 2 0
Solution in Wa ter
50 ± 2
25,000 200,000
1
1.03
15
-
45 - 55
- 49
Wa ter, Alcohols, Glycols, Esters, Wa ter Miscible Solvents
- 49
Alcohols, Esters; Aroma tic and Chlorina ted Hydrocarbons
Polyvin yl Methyl Lutonal M 40 70% Ethanol
8
Solubility
Solution in Ethanol
70 ± 2
50,000 250,000
500
-
1.17
A very light weight, high tensile strength, light stabilizer specially developed to protect carbon fiber reinforced materials. Suitable for high-end transportation coatings.
Product
18
Transportation
Wood
Po wder
Industrial
Description and A pplica tions
UV absorber dispersion for wa terborne coa tings tha t is suited for high performance industrial and decora tive coa ting a pplica tions. Specially blended light stabilizer for po wder and industrial coa tings a pplica tions. HALS that provides significant improvement in coatings performance by minimizing paint defects such as cracking and gloss reduction for clear coats as well as chalking for pigmented paints.
UV absorber tha t provides outstanding protection to coa tings and light sensitive substra tes and ma terials.
UV absorber tha t provides excellent performance in thin film a pplica tions and automotive and industrial finishes.
19
Luwipal® and Plastopal® Amino Resins Solvent
Solids (wt. %)
Maximum Free Formaldehyde (%)
Viscosity (cps)
Sheer Ra te (s -1 )
Acid Value (mg KOH/g)
Density (g/cm 3 )
Hazen Color Number
Baking Reactivity
Reactivity w/Acids
n-Butanol
71 - 75
0.6
4,000 - 7,000
20.6
50
> 50
> 50
> 50
43
-
-
-
98.5
11
5
6
AAK
96
NA
30
24
liquid
AHK
98
> 50
> 50
> 50
Irgacure 651
solid
BDK
99.5
> 50
30
32
Irgacure 754
liquid
BDK
95
> 50
> 50
> 50
Irgacure 784
solid
Metallocene
97
10
10
5
Irgacure 819
solid
APO
98
6
9
5
Irgacure 819-DW
liquid
APO
NA
NA
NA
Irgacure 907
solid
AAK
35
25
22
Irgacure 1700
liquid
APO
> 50
> 50
> 50
Irgacure 1800
solid
APO
27
20
NA
Irgacure 2022
liquid
APO
NA
> 50
> 50
> 50
Irgacure 2100
liquid
APO
NA
> 50
> 50
> 50
Irgacure 2959
solid
AHK
97
3
50
> 50
> 50
NA
NA 98 NA 98
8
40
9
* AAK: Alpha-Amino-Ketones, AHK: Alpha-Hydroxy-Ketones, APO: Acyl-Phosphine-Oxides, BDK: Benzyldimethyl-Ketals, BP: Benzophenone, PLC: Photola tent Ca talyst
25
Joncryl® Acrylic Powder Resins
Physical Properties
Key Benefits
Functionality
Acid/ Hydroxyl Number
Equivalent Weight
Molecular Weight
Softening Point (°C)
Glass Transition Temp. (Tg °C)
Chemistr y
Joncr yl 587
Hydroxyl
92
610
18,000
110
60
Urethane
Acr ylic polyol designed for UV resistant po wder coa tings.
Joncr yl 804
Carboxyl/ Hydroxyl
15/45
1,300
12,500
105
60
Urethane
Acr ylic polyol designed for UV resistant po wder coa tings.
Joncr yl 682
Carboxyl
238
236
1,700
105
56
Hybrid
Acr ylic resin for semi-gloss acr ylic hybrid po wder coa tings.
Joncr yl 815
Carboxyl
38
1,476
10,000
105
55
Hybrid
Acrylic resin for 70/30 acrylic hybrid powder coatings; excellent compatibilizer.
Joncr yl 817
Carboxyl
55
1,020
14,000
120
68
Hybrid
Acr ylic resin for 60/40 acr ylic hybrid po wder coa tings.
Joncr yl 819/820
Carboxyl
75
748
15,000
115
57
Hybrid
Acr ylic resin for 50/50 acr ylic hybrid po wder coa tings.
Joncr yl 821/822
Carboxyl
70
800
10,500
112
62
Hybrid
Acr ylic resin for 50/50 acr ylic hybrid po wder coa tings.
Joncr yl 843
Carboxyl
204
275
6,100
140
86
Hybrid
Acr ylic resin for ultra lo w gloss acr ylic hybrid po wder coa tings.
Joncr yl 845
Carboxyl
240
233
2,400
-
78
Hybrid
Acrylic resin for gloss control in acrylic hybrid powder coatings; excellent pigment dispersion; suitable for low temperature cure (140°C).
Joncr yl 848
Carboxyl
215
261
4,500
127
67
Hybrid
Acr ylic resin for gloss control in acr ylic hybrid po wder coa tings; also used as a sole acr ylic for ultra lo w gloss.
Joncr yl 1850
Glycid yl
-
550
21,000
-
55
-
Product
Appearance
Chemical Resistance
Corrosion Resistance
Flexibility
Flo w
Hardness
Description and A pplica tions
Hydroxyl Acrylics
Carboxyl Acrylics
GMA Acrylics
26
Acrylic resin for exterior durable low gloss powder coatings. Excellent durability.
27
U.S. and Canada BASF Corporation Resins 1609 Biddle Avenue Wyandotte, MI 48192 Phone: +800-231-7868 Fax: +800-392-7429 e-mail:
[email protected] internet: www.basf.com/naftaresins Mexico BASF Mexicana, S.A. de C.V. Av. Insurgentes Sur 975 Col. Ciudad de los Deportes 03710 Mexico, D.F. Phone: +52-55-5325-2787 +52-55-5325-2687 Fax: +52-55-5611-4897
T h e s t a t e m e n t s i n t h e p ro d u c t l i t e r a t u re a n d l a b e l a re g u i d e l i n e s o n l y. U s e r s s h o u l d t e s t t h i s p ro d u c t i n a d v a n c e t o v e r i f y s u i t a b i l i t y f o r particular uses. BASF Corporation neither makes nor authorizes to be m a d e a n y e x p re s s o r i m p l i e d re p re s e n t a t i o n o r w a r r a n t y w i t h re g a rd t o t h i s p ro d u c t c o n c e r n i n g t h e p e r f o r m a n c e , u s e , f i t n e s s f o r p a r t i c u l a r p u r p o s e , s u i t a b i l i t y f o r u s e o n a n y s u r f a c e o r m e rc h a n t a b i l i t y o f t h i s p ro d u c t , w h e t h e r u s e d a l o n e o r i n c o m b i n a t i o n w i t h o t h e r p ro d u c t s . T h e f u r n i s h i n g b y u s o f i n f o r m a t i o n a n d p ro d u c t s e i t h e r a s e x p e r i m e n t a l s a m p l e s o r b y s a l e s , c o n t a i n s n o re c o m m e n d a t i o n s re s p e c t i n g t h e u s e o f t h e s e p ro d u c t s o r t h e l a c k o f i n f r i n g e m e n t o f a n y p a t e n t n o r d o e s i t g r a n t a l i c e n s e u n d e r a n y p a t e n t o w n e d b y o u r c o m p a n y. B A S F a s s u m e s n o l i a b i l i t y f o r a n y d a m a g e o f a n y k i n d re g a rd l e s s o f c a u s e , including negligence. A c ro n a l ® , B a s o n a t ® , C h i m a s s o r b ® , D a ro c u r ® , I r g a c u re ® , J o n c r y l ® , L a ro f l e x ® , L a ro p a l ® , L a ro m e r ® , L i g n o s t a b ® , L u c i r i n ® , L u h y d r a n ® , L u t o n a l ® , L u w i p a l ® , P l a s t o p a l ® , S o l v e n o n ® , a n d T i n u v i n ® a re re g i s t e re d t r a d e m a r k s of BASF Corporation. S o l v e s s o ® i s a re g i s t e re d t r a d e m a r k o f E x x o n M o b i l e C o r p o r a t i o n . © 2 0 1 0 B A S F, W y a n d o t t e , M I 4 8 1 9 2 . A l l r i g h t s re s e r v e d . CO Sel Gd v3.0-03/29/10.
