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Synthesis, Structure, and Thermolysis Mechanism of S-Alkoxythiazynes. Toshiaki ... in aqueous alcohols and the reaction of S,S-diaryl-S-fluorothiazynes with sodium alkoxides. ... rangement to N-alkylsulfoximines when kept in an oily state. .... ent ion of 1c via a five-membered transition state, like the ... An ORTEP drawing.